The first reported anionic oxy retro-ene reaction.
نویسندگان
چکیده
Treatment of the diol 6 with KH and 18-C-6 at room temperature gives the cyclopentenone 7 in good yields. Mechanistic analysis reveals that this is the first case of an anionic oxy retro-ene reaction followed by a tandem intramolecular aldol condensation. Reaction: see text.
منابع مشابه
The first method for protection-deprotection of the indole 2,3-pi bond.
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ورودعنوان ژورنال:
- Organic letters
دوره 3 19 شماره
صفحات -
تاریخ انتشار 2001